Topological variability of Zn(ii) and Co(ii) 3D coordination polymers obtained through solvothermal in situdisulfide cleavage?

CrystEngComm Pub Date: 2011-09-12 DOI: 10.1039/C1CE05592E

Abstract

Two three-dimensional coordination polymers were solvothermally prepared through in situ formation of a 2-sulfobenzoic acid ligand from a 2,2′-dithiobisbenzoic acid precursor involving the oxidative cleavage of its disulfide bond. Complex 1 shows neb-e topology, while complex 2 exhibits a scarcely reported twisting chiral dense 75.9 net.

Graphical abstract: Topological variability of Zn(ii) and Co(ii) 3D coordination polymers obtained through solvothermal in situdisulfide cleavage
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