The origin of the second relaxation process in the [Mn12O12(O2CR)16(H2O)4] single-molecule magnets: ‘Jahn–Teller isomerism’ in the [Mn12O12] core
Chemical Communications Pub Date: 1900-01-01 DOI: 10.1039/A906451F
Abstract
The origin of the second, faster relaxation process in Mn12 molecules has been identified as a different relative orientation of the Jahn–Teller elongation axes of the MnIII ions, which we have termed ‘Jahn–Teller isomerism’.
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Journal Name:Chemical Communications
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CAS no.: 89640-58-4