Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates?

RSC Advances Pub Date: 2019-05-22 DOI: 10.1039/C9RA03389K

Abstract

A facile and efficient approach to phosphoramidates was developed via amination of phosphoryl azides. A variety of phosphoramidates were obtained in one step with good to excellent yields under a mild reaction system. The process uses easily available amines as a N source and offers a new opportunity for P–N bond formation.

Graphical abstract: Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates
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