Total synthesis and stereochemical assignment of cryptolatifolione?
RSC Advances Pub Date: 2015-06-10 DOI: 10.1039/C5RA09186A
Abstract
An enantioselective total synthesis of cryptolatifolione and its C-8 epimer is presented in a protecting-group-free fashion. The synthesis relied on the use of a catalytic double Krische allylation, catalytic olefin metathesis and a C–H oxidation. Comparison of spectroscopic data of the synthetic isomers and natural product made possible the unambiguous elucidation of the absolute configuration of cryptolatifolione.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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