Synthesis and structure of [Na4(DMSO)15][(I3)3(I)]. Self-assembly of hexacoordinated sodium??

Chemical Communications Pub Date: 2011-05-26 DOI: 10.1039/C1CC11898F

Abstract

A new complex with the molecular formula [Na4(DMSO)15][(I3)3(I)] represents the first example of Na+ coordinated solely by DMSO. The triiodide (I3?) and iodide (I?) anions form an infinite linear chain running throughout the crystal.

Graphical abstract: Synthesis and structure of [Na4(DMSO)15][(I3)3(I)]. Self-assembly of hexacoordinated sodium
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