AgSbF6-Catalyzed anti-Markovnikov hydroboration of terminal alkynes?
Chemical Communications Pub Date: 2018-12-21 DOI: 10.1039/C8CC07499B
Abstract
AgSbF6-Catalyzed anti-Markovnikov addition of pinacolborane (HBpin) to terminal alkynes to produce the E-vinylboronates is reported. This efficient methodology is scalable, compatible with sterically and electronically diverse alkynes, and works at room temperature under solvent-free condition. The utility of this method is demonstrated in the facile synthesis of the clinically important (E)-2,4,3′,5′-tetramethoxystilbene.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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