Synthesis and application of PNP pincer ligands in rhodium-catalyzed hydroformylation of cycloolefins?
RSC Advances Pub Date: 2016-10-31 DOI: 10.1039/C6RA24144A
Abstract
Two new phosphorus ligands (L1 and L2) were developed for rhodium-catalyzed hydroformylation of cycloolefins. L1 produced high conversion for cyclohexene (94.7%) and high dialdehyde selectivity for NBD (97.1%) and DCPD (98.4%). Analogue pincer ligands L3–L6 with different steric and electronic character were also investigated in these hydroformylations.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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