Synthesis of a linear polymer from an AB2 monomer of 1-(3-phenoxypropyl)piperidine-4-one in trifluoromethanesulfonic acid

Polymer Chemistry Pub Date: 2011-06-07 DOI: 10.1039/C1PY00178G

Abstract

A linear polymer was successfully prepared by self-polycondensation of 1-(3-phenoxypropyl)piperidine-4-one as an AB2 monomer, which was previously reported to produce a hyperbranched polymer (HBP) with 100% degree of branching (DB). Based on results of the model reaction, the DB could be controlled by changing the acidity of polymerization media.

Graphical abstract: Synthesis of a linear polymer from an AB2 monomer of 1-(3-phenoxypropyl)piperidine-4-one in trifluoromethanesulfonic acid
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