Versatile synthesis of reversible comb-shaped supramolecular polymers?
Polymer Chemistry Pub Date: 2013-12-16 DOI: 10.1039/C3PY01330H
Abstract
We report a modular synthesis method toward precisely defined hydrogen-bonded polyacrylates. Various stickers are built into difunctional ATRP (Atom Transfer Radical Polymerization) initiators, which then allow the formation of polyacrylates with self-complementary stickers in the middle of the chain, the molar mass of which can be tuned within a large range (from 3 to 100 kg mol?1). These self-assembling polymers are characterized by FTIR and SANS in solution, showing that comb-shaped supramolecular polymers with a reversible backbone can be obtained.
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Journal Name：Polymer Chemistry
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CAS no.: 89640-58-4
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