Uniform and simultaneous orthogonal functionalization of a metal–organic framework material?

Molecular Systems Design & Engineering Pub Date: 2020-03-05 DOI: 10.1039/C9ME00182D

Abstract

We exploit orthogonal chemical reactivity to generate uniformly multifunctionalized confined spaces. A metal–organic framework (MOF) material that has azide and hydroxyl reactive groups in well-defined locations is independently functionalized to yield a uniformly bifunctionalized material via multiple paths, including via a simultaneous, one-pot reaction.

Graphical abstract: Uniform and simultaneous orthogonal functionalization of a metal–organic framework material
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