Steering with light: indexable photomotility in liquid crystalline polymers?

RSC Advances Pub Date: 2017-11-13 DOI: 10.1039/C7RA10619J

Abstract

Harnessing light to achieve manipulation and motility in meso and mm-scale systems offers the ability to remotely trigger actuation without requiring on-board power. Central to achieving macroscopic photomotility is the generation of asymmetric interaction between the light-responsive actuator and a substrate. Here, we demonstrate a facile route for achieving indexable, stepped translation of structures fabricated from azobenzene-functionalize liquid crystalline polymers (ALCP). The symmetry breaking in the dynamics of coiling (during irradiation) and uncoiling (when the light is turned off) as a function of the director orientation in splayed ALCP strips leads to asymmetric reaction forces in the interaction with a surface. The broken symmetry leads to directional translation of the center of mass in discrete steps for each on/off cycle of irradiation. Creating composite structures offers a route for hard-coding the trajectories of motility across a range of trajectories that are either rectilinear or curvilinear. Expanding this approach can offer a framework for achieving steerable light-powered microrobots that can translate on arbitrary surface topographies.

Graphical abstract: Steering with light: indexable photomotility in liquid crystalline polymers
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