Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids?
Organic & Biomolecular Chemistry Pub Date: 2014-03-27 DOI: 10.1039/C4OB00294F
Abstract
A simple, fast and efficient method for allylation and propargylation of chlorosilanes through zinc mediation and ultrasound promotion is reported. As a direct application of the resulting bis-allylsilanes, three novel, constrained sila amino acids are prepared for the first time. The design and synthesis of the constrained sila analogue of GABA (γ-amino butyric acid) is a highlight of this work.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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