Transition metal- and solvent-free double hydroboration of nitriles?
Green Chemistry Pub Date: 2020-01-29 DOI: 10.1039/C9GC04260A
Abstract
A highly efficient, room temperature double hydroboration of nitriles under transition metal-free and solvent-free conditions is reported. Sodium triethylborohydride is used as a catalyst and yields up to 99% are disclosed. Mechanistic studies reveal the reaction proceeds in a stepwise manner with initial formation of a boryl-imine which undergoes a second hydroboration to afford a diborylated amine product.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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