Stereoselective synthesis of (Z)-α-halo-α,β-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese?

Organic & Biomolecular Chemistry Pub Date: 2007-12-21 DOI: 10.1039/B717513B

Abstract

Preliminary results of a Mn-promoted sequential process directed toward the stereoselective synthesis of different (Z)-α-halo-α,β-unsaturated compounds are described.

Graphical abstract: Stereoselective synthesis of (Z)-α-halo-α,β-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese
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