The synthesis of planar chiral pseudo-gem aminophosphine pre-ligands based on [2.2]paracyclophane?
Organic & Biomolecular Chemistry Pub Date: 2017-10-12 DOI: 10.1039/C7OB02393F
Abstract
The synthesis of three planar chiral pseudo-gem disubstituted [2.2]paracyclophane-derived P,N-pre-ligands is reported along with preliminary results of their activity in the amination of aryl bromides and chlorides. The pseudo-gem aminophosphines were capable of mediating the coupling reaction at a loading of 1 mol%.
![Graphical abstract: The synthesis of planar chiral pseudo-gem aminophosphine pre-ligands based on [2.2]paracyclophane](http://scimg.chem960.com/usr/1/C7OB02393F.jpg)
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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