SO2F2 mediated dehydrative cross-coupling of alcohols with electron-deficient olefins in DMSO using a Pd-catalyst: one-pot transformation of alcohols into 1,3-dienes?
Organic Chemistry Frontiers Pub Date: 2019-02-02 DOI: 10.1039/C8QO01388H
Abstract
A Pd-catalyzed, SO2F2 mediated dehydrative cross-coupling reaction of alcohols with acrylates for the construction of 1,3-dienes was developed. The reaction proceeded efficiently under mild conditions and tolerated a wide range of functional groups. This new reaction provided a strategically distinct approach to highly valuable 1,3-diene derivatives from readily available and abundant alcohols.
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Journal Name：Organic Chemistry Frontiers
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CAS no.: 89640-58-4
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