Allyl borates: a novel class of polyhomologation initiators?
Chemical Communications Pub Date: 2016-12-22 DOI: 10.1039/C6CC09047H
Abstract
Allyl borates, a new class of monofunctional polyhomologation initiators, are reported. These monofunctional initiators are less sensitive and more effective towards polymethylene-based architectures. As an example, the synthesis of α-vinyl-ω-hydroxypolymethylenes is given. By designing/synthesizing different allylic borate initiators, and using 1H and 11B NMR spectroscopy, the initiation mechanism was elucidated.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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