Additive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst?
Catalysis Science & Technology Pub Date: 2021-12-08 DOI: 10.1039/D1CY01626A
Abstract
Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and aliphatic amines to methylamines. The reaction proceeds via a formylation/transfer hydrogenation pathway over a solid Pd/In2O3 catalyst without the need for any additive.
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Journal Name:Catalysis Science & Technology
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CAS no.: 89640-58-4