Simple synthesis of [Ru(CO3)(NHC)(p-cymene)] complexes and their use in transfer hydrogenation catalysis?
Dalton Transactions Pub Date: 2021-08-16 DOI: 10.1039/D1DT02098F
Abstract
A novel, efficient and facile protocol for the synthesis of a series of [Ru(NHC)(CO3)(p-cymene)] complexes is reported. This family of Ru-NHC complexes was obtained from imidazol(in)ium tetrafluoroborate or imidazolium hydrogen carbonate salts in moderate to excellent yields, employing sustainable weak base. The ruthenium complexes were successfully utilized in the transfer hydrogenation of ketones as highly active multifunctional catalysts.
![Graphical abstract: Simple synthesis of [Ru(CO3)(NHC)(p-cymene)] complexes and their use in transfer hydrogenation catalysis](http://scimg.chem960.com/usr/1/D1DT02098F.jpg)
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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