Stereoselective one-pot synthesis of β-alkylsulfide enol esters. Base-triggered rearrangement under mild conditions?
Organic & Biomolecular Chemistry Pub Date: 2014-07-02 DOI: 10.1039/C4OB01011F
Abstract
A stereoselective one-pot procedure was developed to prepare S-substituted (Z)-enol esters through a base-triggered rearrangement. This transition metal-free multicomponent approach can be performed under an air atmosphere at room temperature, tolerates a wide set of chemical functionalities and generally affords high isolated yields. The (Z)-selectivity arises from the [1,4]-S- to O-acyl migration.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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