A stereoselective, Sm(ii)-mediated approach to decorated cis-hydrindanes: synthetic studies on faurinone and pleuromutilin??
Organic & Biomolecular Chemistry Pub Date: 2011-01-07 DOI: 10.1039/C0OB01086C
Abstract
The cis-hydrindane motif is found in a number of natural products that display important biological activity. A flexible, stereoselective approach to the framework has been developed that features highly diastereoselective, SmI2-mediated cyclisations. The strategy has been exploited in the first synthesis of the proposed structure of faurinone and an approach to the skeleton of the antibacterial natural product,
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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