Three-component difluoroalkylation–thiolation of alkenes by iron-facilitated visible-light photoredox catalysis?

Chemical Communications Pub Date: 2019-03-19 DOI: 10.1039/C9CC00730J

Abstract

The first difluoroalkylation–thiolation of alkenes catalyzed by iron-facilitated photoredox has been developed. The Csp3–Csp3 and Csp3–S bonds were simultaneously constructed smoothly under mild conditions. The reaction exhibits a broad substrate scope of alkenes and thiols with good to excellent yields.

Graphical abstract: Three-component difluoroalkylation–thiolation of alkenes by iron-facilitated visible-light photoredox catalysis
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