Stereocontrolled synthesis of quaternary cyclopropyl esters?

Chemical Communications Pub Date: 2010-07-13 DOI: 10.1039/C0CC01333A

Abstract

Treatment of a variety of enantiopure terminal epoxides with the anion of a range of 2-substituted triethylphosphonoacetates leads to an array of quaternary cyclopropyl esters with high yield and diastereocontrol.

Graphical abstract: Stereocontrolled synthesis of quaternary cyclopropyl esters
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