Activated lipidic cyclic carbonates for non-isocyanate polyurethane synthesis?
Polymer Chemistry Pub Date: 2016-01-11 DOI: 10.1039/C5PY01964H
Abstract
Activated 5-membered cyclic carbonates were prepared from glycerol and fatty acid derivatives. Ester and ether moieties were introduced in the β position to the cyclic carbonate, in order to enhance its reactivity towards amines. 1H NMR kinetic investigation of the aminolysis of these cyclic carbonates demonstrated a higher reactivity compared to the one of alkyl substituted cyclic carbonates. In the case of ester-activated carbonates, a reactivity similar to the one of 6-membered ring cyclic carbonates was observed. Moreover, these carbonates exhibited amidation side-reactions with amines that could be however prevented by decreasing the temperature to room temperature. Poly(hydroxyurethane)s (PHUs) were then synthesized from these activated 5-membered ring cyclic carbonates at 70 °C in DMF (1 mol L?1) and exhibited molar masses up to 13?700 g mol?1 with Tg in the range ?26 to ?10 °C.
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Journal Name：Polymer Chemistry
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CAS no.: 89640-58-4
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