Selective catalytic oxidation of diglycerol?
Green Chemistry Pub Date: 2021-01-22 DOI: 10.1039/D0GC03239E
Abstract
The selective oxidation of α,α-diglycerol was studied using oxygen as a clean oxidant in the presence of a palladium/neocuproine complex. After optimization of the reaction parameters, the mono-oxidation product was obtained with 93% NMR yield (up to 76% isolated yield). The product was named “diglycerose” considering that it mainly exists as a cyclic hemi-ketal form.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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