Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines?
Chemical Science Pub Date: 2016-07-04 DOI: 10.1039/C6SC02129H
Abstract
A homoleptic scandium trialkyl complex in combination with a borate compound served as an excellent catalyst for the C–H addition of aliphatic tertiary amines to olefins. This highly regiospecific, 100% atom efficient C–H bond alkylation reaction was applicable to a wide variety of tertiary amines and olefins, including functionalised styrenes and unactivated α-olefins. This work represents the first example of rare-earth catalysed olefin hydroaminoalkylation and also the first example of catalytic C–H addition of aliphatic tertiary amines to olefins with any catalyst.
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Journal Name：Chemical Science
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CAS no.: 89640-58-4
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