Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine?
Dalton Transactions Pub Date: 2014-09-04 DOI: 10.1039/C4DT02279C
Abstract
Three gold(III) complexes with terminal amido ligands were prepared by the reaction of [AuIII(trpy)(OH)](ClO4)2 and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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