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A soluble iron(ii)-phthalocyanine-catalyzed intramolecular C(sp3)–H amination with alkyl azides?

Chemical Communications Pub Date: 2021-09-23 DOI: 10.1039/D1CC04573C

Abstract

Herein, we describe a soluble iron(II)-phthalocyanine, [Fe^II(^tBu₄Pc)(py)₂] (Pc = phthalocyaninato(2–)), as an effective catalyst in intramolecular C(sp³)–H bond amination, with alkyl azides as the nitrogen source, to afford the amination products in moderate to excellent yields with a broad substrate scope.

Graphical abstract: A soluble iron(ii)-phthalocyanine-catalyzed intramolecular C(sp3)–H amination with alkyl azides

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Chemical Communications

Journal Name：Chemical Communications

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