Schiff-base macrocyclic ZnII complexes based upon flexible pendant-armed extended dialdehydes?

Dalton Transactions Pub Date: 2018-11-08 DOI: 10.1039/C8DT03894E

Abstract

This Frontier article reviews diverse structures of Schiff-base macrocyclic ZnII complexes derived from a family of flexible pendant-armed extended dialdehydes via a preorganized synthetic strategy and the corresponding structure-determining factors, including primary cationic template effects and secondary complementary template effects. In addition, further post-modification and supramolecular self-assembly of Schiff-base ZnII macrocycles and their possible applications in a variety of areas have been discussed.

Graphical abstract: Schiff-base macrocyclic ZnII complexes based upon flexible pendant-armed extended dialdehydes
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