The impact of grafted surface defects and their controlled removal on supramolecular self-assembly?
Chemical Science Pub Date: 2016-07-25 DOI: 10.1039/C6SC02400A
Abstract
We demonstrate the use of covalently modified graphite as a convenient and powerful test-bed for the versatile investigation and control of 2-D crystallization at the liquid solid interface. Grafted aryls act as surface defects and create barriers to supramolecular self-assembly. An easily tunable grafting density allows for varying the effect of such defects on supramolecular self-assembly. Finally, the defects can be locally removed, triggering monolayer reconstructions and allowing in situ investigations of thermodynamically unstable or metastable morphologies.
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Journal Name：Chemical Science
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CAS no.: 89640-58-4
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