Rhodium(iii)-catalyzed C–C coupling of 7-azaindoles with vinyl acetates and allyl acetates?
Organic & Biomolecular Chemistry Pub Date: 2015-11-04 DOI: 10.1039/C5OB02096D
Abstract
The behaviour of electron-rich alkenes with 7-azaindoles in rhodium(III)-catalyzed C–H activation is investigated. Various substituted vinyl acetates and allyl acetates as coupling partners reacted smoothly providing a wide variety of 7-azaindole derivatives, and the selectivity of the coupling reaction is alkene-dependent. In addition, the approaches of rhodium(III)-catalyzed dehydrogenative Heck-type reaction (DHR) and carbonylation reaction were quite novel and simple.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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