Remarkable adsorptive removal of nitrogen-containing compounds from hydrotreated fuel by molecularly imprinted poly-2-(1H-imidazol-2-yl)-4-phenol nanofibers?

RSC Advances Pub Date: 2018-02-20 DOI: 10.1039/C8RA00543E

Abstract

Molecularly imprinted polymer (MIP) nanofibers were prepared by the electrospinning of poly 2-(1H-imidazol-2-yl)-4-phenol (PIMH) in the presence of various nitrogen containing compounds (N-compounds). Molecularly imprinted polymer nanofibers show selectivity for various target model nitrogen-containing compounds with adsorption capacities of 11.7 ± 0.9 mg g?1, 11.9 ± 0.8 mg g?1 and 11.3 ± 1.1 mg g?1 for quinoline, pyrimidine and carbazole, respectively. Molecular modelling based upon density functional theory (DFT) indicated that hydrogen bond interactions may take place between the lone-pair nitrogen atom of model compounds (quinoline and pyrimidine) and the –OH and –NH groups of the PIMH nanofibers. The adsorption mode followed the Freundlich (multi-layered) adsorption isotherm, which indicated possible nitrogen–nitrogen compound interactions. Molecularly imprinted polymer nanofibers show potential for the removal of nitrogen-containing compounds in fuel.

Graphical abstract: Remarkable adsorptive removal of nitrogen-containing compounds from hydrotreated fuel by molecularly imprinted poly-2-(1H-imidazol-2-yl)-4-phenol nanofibers
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