Silver-mediated radical cyclization: construction of Δ2-isoxazolines from α-halo ketoximes and 1,3-dicarbonyl compounds?
Chemical Communications Pub Date: 2014-05-01 DOI: 10.1039/C4CC02084G
Abstract
A novel route to Δ2-isoxazolines is presented via silver-mediated radical cyclization of α-halo ketoximes with 1,3-dicarbonyl compounds. This method is performed using a radical strategy, and represents a new example of silver-initiated generation of oxime radicals for the formation of the C(sp3)–O bonds.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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