Regioselective palladium-catalysed coupling reactions of vinyl chlorides with carbon nucleophiles
Chemical Communications Pub Date: 1900-01-01 DOI: 10.1039/A608371D
Abstract
Vinyl chlorides bearing methyl groups in the 2-position can be
activated catalytically by palladium(0)-complexes of
1,4-bis(dicyclohexylphosphino)butane, the process involving
vinyl–allyl isomerization via CH-activation followed by
nucleophilic attack of C-nucleophiles on the intermediate
palladium–π-allyl species.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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