Red-shifted backbone N–H photocaging agents?

Organic & Biomolecular Chemistry Pub Date: 2020-06-09 DOI: 10.1039/D0OB00923G

Abstract

Light is a uniquely powerful tool for spatiotemporal control of molecular structure, necessitating the development of new photocaging approaches. This communication describes the design, synthesis, and reactivity of two new photoreactive boronic acid reagents for backbone N–H modification and subsequent photocleavage.

Graphical abstract: Red-shifted backbone N–H photocaging agents
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