Reductive linear- and cyclo-trimerization of isocyanides using an Al–Al-bonded compound?
Chemical Communications Pub Date: 2019-07-11 DOI: 10.1039/C9CC04344F
Abstract
Dialumane 1 reacts with tBuNC to produce a reductive dimerization adduct [LAl(tBuN![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C–CNtBu)AlL] (2). In the presence of Na, 1 can promote linear- and cyclo-trimerization of isocyanides, affording products [Na][LAl{(tBuNC)3}AlL] (3 and 4) and [Na][LAl{(tBuNC)3}Al(C![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
N)L] (5), the latter of which features a unique aromatic tri(tert-butylimino)deltate dianion [C3N3(tBu)3]2?.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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