Synthetic studies on daphniglaucins?
Chemical Communications Pub Date: 2018-05-03 DOI: 10.1039/C8CC03063D
Abstract
The synthetic approach to the core framework of daphniglaucin-type Daphniphyllum alkaloids is described herein. The B–C ring was constructed via a Rh-catalyzed [3+2] cycloaddition. Continuous quaternary centers were installed through [3+2] cycloaddition and alkylation. The attempt to build the A–D ring motif using dipolar cycloaddition of azomethine ylides was extensively investigated.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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