A stable and practical nickel catalyst for the hydrogenolysis of C–O bonds?
Green Chemistry Pub Date: 2016-12-05 DOI: 10.1039/C6GC01955B
Abstract
The selective hydrogenolysis of C–O bonds constitutes a key step for the valorization of biomass including lignin fragments. Moreover, this defunctionalization process offers the possibility of producing interesting organic building blocks in a straightforward manner from oxygenated compounds. Herein, we demonstrate the reductive hydrogenolysis of a wide variety of ethers including diaryl, aryl–alkyl and aryl–benzyl derivatives catalyzed by a stable heterogeneous NiAlOx catalyst in the presence of a Lewis acid (LA). The special feature of this catalyst system is the formation of substituted cyclohexanols from the corresponding aryl ether.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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