Synthesis, structure and spectroscopic analyses of aquachloridooxidodiperoxidomolybdate(vi)??

Dalton Transactions Pub Date: 2013-10-29 DOI: 10.1039/C3DT52848K

Abstract

A novel aquachloridooxidodiperoxidomolybdate(VI), [MoClO(O2)2(OH2)]?, was crystallised as tetraethylammonium and triethylmethylammonium salts from strongly acidic aqueous solutions, and was structurally analysed by single crystal X-ray diffraction and NMR spectroscopy. The aqueous behaviour of the present anion observed by 17O NMR agrees with that reported in a previous speciation study.

Graphical abstract: Synthesis, structure and spectroscopic analyses of aquachloridooxidodiperoxidomolybdate(vi)
Recommended Literature