Synthesis, structure and magnetic properties of copper(ii) azide?
Dalton Transactions Pub Date: 2019-06-29 DOI: 10.1039/C9DT01450K
Abstract
A novel azide-bridged copper compound without an auxiliary ligand has been synthesized and characterized by single-crystal diffraction analysis. The compound consists of 1D double chains with end-on (EO) azide bridges. Furthermore, the neighboring chains are connected by weak coordination bonds, which leads to the formation of a 3D architecture. Low-temperature magnetic measurements reveal that antiferromagnetic interactions are dominant, with concomitant spin-canted antiferromagnetism.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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