Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents?

Dalton Transactions Pub Date: 2013-07-08 DOI: 10.1039/C3DT51120K

Abstract

Herein we report the synthesis of α-Dawson type POM, Li6[α-P2W18O62]·28H2O, directly from the use of Li2WO4 as the tungstate source. The salt obtained was soluble not only in water but also in a range of polar and non-polar organic solvents, such as benzene.

Graphical abstract: Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents
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