Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation?
Chemical Communications Pub Date: 2014-10-13 DOI: 10.1039/C4CC07648F
Abstract
Three chiral robust diene-based porous organic frameworks (POFs) are prepared. POF-1 is shown to be an efficient heterogeneous catalyst after metallation for asymmetric conjugation addition with up to 93% ee, and it can also function as a new chiral stationary phase for gas chromatographic separation of racemates.
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Journal Name：Chemical Communications
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