The control of the morphologies, structures and photoluminescence properties of C70 nano/microcrystals with different trichlorobenzene isomers
CrystEngComm Pub Date: 2014-01-06 DOI: 10.1039/C3CE42201A
Abstract
Trichlorobenzene isomers with different molecular structures (1,2,3-, 1,2,4- and 1,3,5-trichlorobenzene) were used as shape and luminescence tuners of C70 nano/microcrystals. C70 nano/microcrystals with different morphologies (nano/microrods, nano/microsheet clusters and nano/microballs) were synthesized. C70 nano/microballs fabricated using 1,3,5-trichlorobenzene have a simple cubic (sc) structure, and C70 nano/microcrystals obtained using other solvents have a face-centered-cubic (fcc) structure. Meanwhile, the introduction of different trichlorobenzenes in the C70 nano/microcrystals enhanced their PL intensities to different degrees. In particular, the PL intensities of the C70 nano/microcrystals doped with 1,3,5-trichlorobenzene were most highly enhanced, which is one order of magnitude higher than that for the pristine bulk C70 crystals.
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Journal Name：CrystEngComm
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CAS no.: 89640-58-4
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