Remarkably stable dinuclear, diamagnetic rhenium(VI) salts with the [ReOCl4OReOCl4]2? anion?
Dalton Transactions Pub Date: 2009-03-31 DOI: 10.1039/B823327F
Abstract
A reaction leading reproducibly to the stable salts containing μ-oxido-bis{cis-tetrachloridooxidorhenate(VI)} anion (systematic name: μ-oxido-bis{(OC-6-32)-tetrachloridooxidorhenate(VI)} anion) was described. A series of phosphonium salts was prepared in crystalline form and a detailed investigation of the complex anion structure was performed. The magnetic and spectroscopic properties are discussed on the example of the methyltriphenylphoshonium salt.
![Graphical abstract: Remarkably stable dinuclear, diamagnetic rhenium(VI) salts with the [ReOCl4OReOCl4]2? anion](http://scimg.chem960.com/usr/1/B823327F.jpg)
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Journal Name：Dalton Transactions
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