Activation of [99(m)TcO4]? by phosphonium cations?

Chemical Communications Pub Date: 2014-02-26 DOI: 10.1039/C4CC00718B

Abstract

Phosphonium salts in solution or bound to solid phase supports interact with the robust [99(m)TcO4]? anion in neutral water. This activated form of [99(m)TcO4]? represents a source for complexes with the fac-{99mTcVIIO3}+ core, which can be synthesized in high yields and purity.

Graphical abstract: Activation of [99(m)TcO4]? by phosphonium cations
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