Porphyrin-based mixed-valent Ag(i)/Ag(ii) and Cu(i)/Cu(ii) networks as efficient heterogeneous catalysts for the azide–alkyne “click” reaction and promising oxidation of ethylbenzene?
Chemical Communications Pub Date: 2015-11-30 DOI: 10.1039/C5CC08456C
Abstract
By using a new porphyrin-based linker, two unusual mixed-valent Ag(I,II)– and Cu(I,II)–organic networks were synthesized. Most strikingly, 1 and 2 exhibit highly efficient catalytic activities for the azide–alkyne “click” reaction and oxidation of ethylbenzene.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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