Synthesis of d-erythro-sphingosine and d-erythro-ceramide
Chemical Communications Pub Date: 2002-02-01 DOI: 10.1039/B111071N
Abstract
A 1,2-metallate rearrangment of a higher order cuprate derived from an α-lithiated xylal derivative and tridecyllithium is the key step in a synthesis of D-erythro-sphingosine and ceramide. A convenient method for preparing α-lithiated glycals from α-phenylsulfinyl glycals is also described.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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