Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst?
Chemical Communications Pub Date: 2017-08-08 DOI: 10.1039/C7CC05221A
Abstract
A convenient method for the synthesis of borasiloxanes from silanes and pinacolboranes using Cu3(BTC)2 as a heterogeneous catalyst in acetonitrile at 70 °C is reported. This procedure is more convenient than Ru and Pd based homogeneous catalysts because it avoids the use of noble metals, easy handling of starting materials and the catalyst can be reused.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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