Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network?

Chemical Communications Pub Date: 2011-10-14 DOI: 10.1039/C1CC15053G

Abstract

A coordination network comprising 2-vinyltriphenylene was treated with AIBN at a high temperature, but the radical polymerization of the vinyl monomer was completely suppressed by spatial separation and otherwise hidden aerobic oxidation pathways are enhanced.

Graphical abstract: Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network
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