Photo-induced variation of magnetism in coordination polymers with ligand-based electron transfer

Dalton Transactions Pub Date: 2021-08-09 DOI: 10.1039/D1DT01963E

Abstract

Photo-induced variation of magnetism from ligand-based electron transfer has been extensively studied because of its potential applications in magneto-optical memory devices, light-responsive switches, and high-density information storage materials. In this review, we discussed the progress in the photo-induced variation of magnetism in coordination polymers with ligand-to-metal charge transfer (LMCT), ligand-to-ligand charge transfer (LLCT) and internal ligand charge transfer (ILCT), which provides fundamentals for the rational design of multi-functional materials. We also discussed the design and synthetic strategy of such molecule-based materials and gave views on the current challenges and growth trends in this field.

Graphical abstract: Photo-induced variation of magnetism in coordination polymers with ligand-based electron transfer
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